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• W2036185846 endingPage "2272" @default.
• W2036185846 startingPage "2265" @default.
• W2036185846 abstract "Energy distributions of photoelectrons from evaporated films of rubidium halides were measured in the photon energy range 10-27 eV. Density-of-states structures above the vacuum level are observed for all rubidium halides. Valence-band photoelectron spectra indicate splittings of 0.5 ifmmodepmelsetextpmfi{} 0.2 and 1.0 ifmmodepmelsetextpmfi{} 0.2 eV in the ${mathrm{Br}}^{ensuremath{-}}$ $4p$ and ${mathrm{I}}^{ensuremath{-}}$ $5p$ bands, respectively. Density-of-states calculations using a Slater-Koster interpolation in RbCl and a relativistic tight-binding interpolation scheme in RbBr and RbI were performed and the results are in reasonable agreement with the observed valence bandwidths and spin-orbit splittings. In the ${mathrm{Rb}}^{+}$ $4p$ core spectra, a spin-orbit splitting of 0.9 ifmmodepmelsetextpmfi{} 0.3 eV can be seen. The total width of the ${mathrm{Rb}}^{+}$ $4p$ core spectrum of RbF is found to increase with temperature in accordance with the model of phonon broadening." @default.
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• W2036185846 date "1977-02-15" @default.
• W2036185846 modified "2023-09-29" @default.
• W2036185846 title "Ultraviolet photoelectron spectra of rubidium halides" @default.
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• W2036185846 doi "https://doi.org/10.1103/physrevb.15.2265" @default.
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