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- W2036186354 abstract "New silver(I) complexes have been synthesised from the reaction of AgNO3, monodentate PR3 (PR3 = P(o-tolyl)3, P(m-tolyl)3, P(p-tolyl)3, P(p-C6H4F), SeP(C6H5)3) or bidentate tertiary (dppe = bis(diphenylphosphane)ethane, dppf = 1,1′-bis(diphenylphosphane)ferrocene) phosphanes and potassium dihydrobis(3-nitro-1,2,4-triazolyl)borate, K[H2B(tzNO2)2]. These compounds have been characterized by elemental analyses, FT-IR, ESI-MS and multinuclear (1H and 31P) NMR spectral data. The adduct {[H2B(tzNO2)2]Ag[P(m-tolyl)3]2} has been characterized by single crystal X-ray studies. In the former, the H2B(tzNO2)2 acts as a monodentate ligand utilizing the coordinating capability of only one of the additional (exo-) ring nitrogens to complete the coordination array about the silver atom." @default.
- W2036186354 created "2016-06-24" @default.
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- W2036186354 date "2007-04-01" @default.
- W2036186354 modified "2023-10-09" @default.
- W2036186354 title "Silver(I)-organophosphane complexes of the dihydridobis(3-nitro-1,2,4-triazolyl)borate ligand. X-ray crystal structure of {[H2B(tzNO2)2]Ag[P(m-tolyl)3]2} with the scorpionate ligand co-ordinated in an unidentate κ1-N fashion" @default.
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- W2036186354 doi "https://doi.org/10.1016/j.ica.2006.10.030" @default.
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