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- W2036209238 abstract "The crystal structure of Hg(3)AlF(6)O(2)H, trimercury(II) aluminium hydrogen hexafluoride dioxide, can be derived from a slightly distorted cubic close-packed (ccp) arrangement of the metal atoms, where three quarters of the positions are occupied by Hg atoms and one quarter by Al atoms. The F and O atoms are considerably dislocated from the tetrahedral voids of this arrangement, thus forming [HgO(2)F(6)] polyhedra, with two short Hg-O distances, two intermediate Hg-F distances and four longer Hg-F distances, and nearly ideal [AlF(6)] octahedra. The H atoms are presumably located close to the inversion centre. Their positions were derived from crystal chemical arguments, and they take part in the formation of O-H.O hydrogen bonds between two O atoms, with an O.O distance of 2.562 (9) A." @default.
- W2036209238 created "2016-06-24" @default.
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- W2036209238 date "2002-02-20" @default.
- W2036209238 modified "2023-09-27" @default.
- W2036209238 title "Hg<sub>3</sub>AlF<sub>6</sub>O<sub>2</sub>H, a structure with a short interpolyhedral O...O distance" @default.
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- W2036209238 doi "https://doi.org/10.1107/s0108270102000690" @default.
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