FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036285296> ?p ?o ?g. }

• W2036285296 endingPage "114" @default.
• W2036285296 startingPage "101" @default.
• W2036285296 abstract "Abstract The ligand 3,6,9,17,20,23,28,29-octaazatricyclo[23.3.1.1 11,15 ]tridecanedeca-1(28),2,9,11,13,15(30),16,23,25(29),26-ene (PD) 2 (DIEN) 2 , 1 , was used together with Cu(CH 3 CN) 4 PF 6 to prepare a dinuclear copper(I) complex ( 2 ) which, when oxygenated at 25.0°C produced a copper(II)-dioxygen adduct ( 3 ) as an initial species, which decomposed to a copper(II) complex ( 4 ). The complex cation of 4 was formed by the reaction of 1 with CuCl 2 . It is shown that both 3 and 4 , in the presence of excess dioxygen, catalytically convert hydroquinone, t -butylhydroquinone, 2,6-di- t -butylphenol, 2,6-dimethoxyphenol and 3,5-di- t -butylcatechol to their respective oxidation products benzoquinone, t -butylbenzoquinone, 3,3′5,5′-tetra- t -butyldiphenoquinone, 3,3′,5,5′-tetramethoxydiphenoquinone and 3,5-di- t -butyl-1,2-benzoquinone. Under the same conditions 3 converts 2,4-di- t -butylphenol to 3,3′,5,5′-tetra- t -butyl-2-2′-dihydroxybiphenyl,4- t -butylcatechol to the γ-lactone of 3-hydroxy-4- t -butylmuconic acid ester, and 3,4-dimethylaniline to 3,3′4,4′-tetramethylazobenzene whereas 4 is inactive for these substrates. The complex 4 is found to oxidize 4-methylcatechol; however, for this substrate 3 is inactive. The oxidation of 3,5-di- t -butylcatechol is first order in 3 and zero order in substrate, having a pseudo first order rate constant of 1.3 × 10 −3 s −1 . Under pseudo first order conditions the reaction between 3,5-di- t -butylcatechol and 4 is first order in 4 . The rates of stoichiometric reactions are determined to be greater for reactions with 3 than for those with 4 by factors which range between 5 and 100." @default.
• W2036285296 created "2016-06-24" @default.
• W2036285296 creator A5021837566 @default.
• W2036285296 creator A5074487085 @default.
• W2036285296 date "1995-06-01" @default.
• W2036285296 modified "2023-10-07" @default.
• W2036285296 title "Stoichiometric and catalytic oxidation by a dinuclear copper(I) dioxygen complex and a dinuclear cpper(II) complex of a macrocyclic ligand derived from the 2:2 condensation of pyridine-2,6-dicarboxaldehyde and 1,4,7-triazaheptane" @default.
• W2036285296 cites W1963484597 @default.
• W2036285296 cites W1966114000 @default.
• W2036285296 cites W1966698815 @default.
• W2036285296 cites W1971103998 @default.
• W2036285296 cites W1971515732 @default.
• W2036285296 cites W1973976310 @default.
• W2036285296 cites W1980776941 @default.
• W2036285296 cites W1987141802 @default.
• W2036285296 cites W1988238068 @default.
• W2036285296 cites W1991309699 @default.
• W2036285296 cites W1995076846 @default.
• W2036285296 cites W1996624861 @default.
• W2036285296 cites W2003262187 @default.
• W2036285296 cites W2003720961 @default.
• W2036285296 cites W2007347826 @default.
• W2036285296 cites W2009281210 @default.
• W2036285296 cites W2016193130 @default.
• W2036285296 cites W2022128583 @default.
• W2036285296 cites W2026283109 @default.
• W2036285296 cites W2029320672 @default.
• W2036285296 cites W2032736749 @default.
• W2036285296 cites W2032769985 @default.
• W2036285296 cites W2036591933 @default.
• W2036285296 cites W2039656547 @default.
• W2036285296 cites W2041315640 @default.
• W2036285296 cites W2059652206 @default.
• W2036285296 cites W2061356043 @default.
• W2036285296 cites W2062190250 @default.
• W2036285296 cites W2064681018 @default.
• W2036285296 cites W2071894609 @default.
• W2036285296 cites W2074378489 @default.
• W2036285296 cites W2076707740 @default.
• W2036285296 cites W2079108179 @default.
• W2036285296 cites W2080053026 @default.
• W2036285296 cites W2080617071 @default.
• W2036285296 cites W2082490798 @default.
• W2036285296 cites W2083298328 @default.
• W2036285296 cites W2090155257 @default.
• W2036285296 cites W2091269537 @default.
• W2036285296 cites W2130574803 @default.
• W2036285296 cites W2949468205 @default.
• W2036285296 cites W2951058781 @default.
• W2036285296 cites W3004480158 @default.
• W2036285296 cites W4247548864 @default.
• W2036285296 doi "https://doi.org/10.1016/1381-1169(95)00033-x" @default.
• W2036285296 hasPublicationYear "1995" @default.
• W2036285296 type Work @default.
• W2036285296 sameAs 2036285296 @default.
• W2036285296 citedByCount "20" @default.
• W2036285296 countsByYear W20362852962012 @default.
• W2036285296 countsByYear W20362852962013 @default.
• W2036285296 countsByYear W20362852962014 @default.
• W2036285296 countsByYear W20362852962017 @default.
• W2036285296 crossrefType "journal-article" @default.
• W2036285296 hasAuthorship W2036285296A5021837566 @default.
• W2036285296 hasAuthorship W2036285296A5074487085 @default.
• W2036285296 hasConcept C115624301 @default.
• W2036285296 hasConcept C116569031 @default.
• W2036285296 hasConcept C121332964 @default.
• W2036285296 hasConcept C122922312 @default.
• W2036285296 hasConcept C144082473 @default.
• W2036285296 hasConcept C155647269 @default.
• W2036285296 hasConcept C161790260 @default.
• W2036285296 hasConcept C170493617 @default.
• W2036285296 hasConcept C178790620 @default.
• W2036285296 hasConcept C179104552 @default.
• W2036285296 hasConcept C185592680 @default.
• W2036285296 hasConcept C188027245 @default.
• W2036285296 hasConcept C200093464 @default.
• W2036285296 hasConcept C21951064 @default.
• W2036285296 hasConcept C2779432074 @default.
• W2036285296 hasConcept C2779485729 @default.
• W2036285296 hasConcept C515602321 @default.
• W2036285296 hasConcept C544778455 @default.
• W2036285296 hasConcept C55493867 @default.
• W2036285296 hasConcept C71240020 @default.
• W2036285296 hasConcept C78030364 @default.
• W2036285296 hasConcept C8010536 @default.
• W2036285296 hasConcept C97355855 @default.
• W2036285296 hasConceptScore W2036285296C115624301 @default.
• W2036285296 hasConceptScore W2036285296C116569031 @default.
• W2036285296 hasConceptScore W2036285296C121332964 @default.
• W2036285296 hasConceptScore W2036285296C122922312 @default.
• W2036285296 hasConceptScore W2036285296C144082473 @default.
• W2036285296 hasConceptScore W2036285296C155647269 @default.
• W2036285296 hasConceptScore W2036285296C161790260 @default.
• W2036285296 hasConceptScore W2036285296C170493617 @default.
• W2036285296 hasConceptScore W2036285296C178790620 @default.
• W2036285296 hasConceptScore W2036285296C179104552 @default.
• W2036285296 hasConceptScore W2036285296C185592680 @default.
• W2036285296 hasConceptScore W2036285296C188027245 @default.

• next