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- W2036308106 abstract "Abstract Aqueous hydrogen sulphide solubilities have been determined for distilled water and 1–5 m NaCl brines at temperatures of 25°–95°C at atmospheric pressure. From the experimental data, a set of polynomial equations has been derived which can be used to calculate H2S solubilities for any temperature up to 95 °C and NaCl content up to 5 molal. The results can be applied to the behavior of H2S in natural systems ranging from normal groundwaters to low-temperature geothermal brines; they also allow more accurate calculation of metal sulphide solubilities in acid solutions below 100°C. From the solubility data, activity coefficients of H2S have been calculated. For a given gas and temperature, the relation between activity coefficient values γn and the true ionic strength I is given by the slope bγ,n. For H2S bγ,n is 0.0745 for the 25°–80°C data; values increase to 0.109 at 95°C. H2S solubilities were also calculated for our experimental conditions using an equation presented by Barta and Bradley (1985) which is based on data obtained by Drummond (1981) under higher P-T conditions. Calculated values generally show good agreement with our measured results." @default.
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- W2036308106 date "1988-04-01" @default.
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- W2036308106 title "The solubility of hydrogen sulphide in 0–5 m NaCl solutions at 25°–95°C and one atmosphere" @default.
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- W2036308106 doi "https://doi.org/10.1016/0016-7037(88)90352-3" @default.
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