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- W2036390575 abstract "Heterogeneous chemical systems have been studied for the synthesis of isotactic polypropylene in order to establish baseline parameters for the reaction process and to develop sensitive and accurate methods of analysis. These parameters and analytical methods may be used to make a comparison between the polypropylene obtained at one g with that of zero g (gravity). Baseline reaction parameters have been established for the slurry (liquid monomer in heptane/solid catalyst) polymerization of propylene to yield high purity, 98% isotactic polypropylene. Kinetic data for the slurry reaction showed that a sufficient quantity of polymer for complete characterization can be produced in a reaction time of 5 min; this time is compatible with that available on a sounding rocket for a zero-g simulation experiment. The preformed (activated) catalyst was found to be more reproducible in its activity than the in situ formed catalyst." @default.
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- W2036390575 date "1975-05-27" @default.
- W2036390575 modified "2023-09-24" @default.
- W2036390575 title "Low gravity synthesis of polymers with controlled molecular configuration" @default.
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- W2036390575 doi "https://doi.org/10.2514/6.1975-697" @default.
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