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• W2036391900 endingPage "1806" @default.
• W2036391900 startingPage "1806" @default.
• W2036391900 abstract "The wide diversity of room-temperature ionic liquids (ILs) presents opportunities for studying, and controlling, polymer phase behavior. We have examined the phase behavior of poly(N-isopropyl acrylamide) (PNIPAM) in imidazolium ILs and their mixtures with water. We find there is a strong influence of the IL anion; specifically, the tetrafluoroborate anion yields a complex phase diagram with both LCST and UCST-type regimes. PNIPAM is generally miscible at intermediate IL-water compositions, although this range depends on the polymer molecular weight. Solvatochromatic characterization of both neat and mixed solvents reveals a key role for the interplay between PNIPAM-IL hydrogen-bonding and ion-pairing within the IL. These results demonstrate that appropriate selection of ILs should allow for increased control over polymer phase behavior." @default.
• W2036391900 created "2016-06-24" @default.
• W2036391900 creator A5043645963 @default.
• W2036391900 creator A5068508692 @default.
• W2036391900 creator A5070413067 @default.
• W2036391900 date "2013-01-01" @default.
• W2036391900 modified "2023-09-26" @default.
• W2036391900 title "Critical solution behavior of poly(N-isopropyl acrylamide) in ionic liquid–water mixtures" @default.
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• W2036391900 doi "https://doi.org/10.1039/c2cp44205a" @default.
• W2036391900 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23299223" @default.
• W2036391900 hasPublicationYear "2013" @default.
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