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- W2036392723 abstract "The title reactions give the expected variety of products derived from the radicals formed by loss of iodine. The initial reactions of these radicals are identified as cyclisation to γ- and δ-lactam intermediates, together with a minor amount of 1,5-hydrogen transfer from the N-alkyl group. The δ-lactam intermediates are oxidised to N-alkyl-phenanthridinones, and 1,5-hydrogen transfer results in dealkylation at the nitrogen atom. The γ-lactam intermediates react by several pathways. That from the 2′-methoxy-amide predominantly dimerises, whilst from the 3′-methoxy-amide a major product is a spirocyclohexenone γ-lactam, the result of demethylation at the oxygen atom (possibly catalysed by hydrogen iodide liberated during the reaction)." @default.
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- W2036392723 date "1972-01-01" @default.
- W2036392723 modified "2023-10-14" @default.
- W2036392723 title "Internuclear cyclisation. Part XXX. The photolysis of 2-iodo-2′-, -3′-, and -4′-methoxy-N-alkylbenzanilides in benzene" @default.
- W2036392723 doi "https://doi.org/10.1039/p19720001150" @default.
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