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- W2036403772 abstract "The rate of the degenerate 6,1-hydride shift and rearrangement of the 2-methyl-2-norbornyl cation has been determined using selective pulse transfer experiments and 2D NOESY experiments over the temperature range 200–220 K. Least-squares analysis of the data gives a free energy of activation of 11.3 kcal mol−1. The results are compatible with the presence of σ-delocalization in the 2-methyl-2-norbornyl cation." @default.
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- W2036403772 date "1987-12-01" @default.
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- W2036403772 title "Rate of degenerate rearrangement of the 2-methyl-2-norbornyl cation studied by13C selective pulse transfer and two-dimensional NOESY spectroscopy" @default.
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- W2036403772 doi "https://doi.org/10.1002/mrc.1260251203" @default.
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