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• W2036404338 abstract "Abstract RMn2−xFexD6 compounds were obtained by applying a deuterium pressure of several kbar to RMn2−xFex compounds for x≤0.2 and R=Y, Er. These compounds are isostructural to RMn2D6 compounds and crystallize in a K2PtCl6 type structure with a random substitution of R and half the Mn atoms in the same 8c site whereas the other Mn atoms are located on the 4a site and surrounded by six D atoms (24e site). According to neutron powder diffraction analysis the Fe atoms are preferentially substituted on the 4a site. YMn2−xFexD6 compounds are paramagnetic and their molar susceptibility follows a modified Curie–Weiss law. ErMn2−xFexD6 compounds display a ferromagnetic behavior at 2 K, but their saturation magnetization (MS∼4.0 μB/f.u.) is half that of their parent compounds (MS∼8.0 μB/f.u.). The neutron diffraction patterns of ErMn1.8Fe0.2D6 display below 13 K both ferromagnetic and antiferromagnetic short range order, which can be related to a disordered distribution of Er moments. The paramagnetic temperatures of ErMn2−xFexD6 compounds are negative and decrease versus the Fe content whereas they are positive and increase for their parent compounds." @default.
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• W2036404338 date "2011-02-01" @default.
• W2036404338 modified "2023-10-18" @default.
• W2036404338 title "Structural and magnetic properties of RMn2−Fe D6 compounds (R=Y, Er; x≤0.2) synthesized under high deuterium pressure" @default.
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• W2036404338 doi "https://doi.org/10.1016/j.jssc.2010.12.017" @default.
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