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- W2036420281 abstract "We present a study of emission, absorption and vibrational properties of Sm3+ doped lead fluoroborate glasses (PbO–PbF2–B2O3–Sm2O3) as a function of the Sm3+ content. Changes in the position and the intensity parameters of the transitions are closely related to structural changes in the glass network. A Judd–Ofelt scheme was used to estimate the intensity parameters Ωλ and radiative properties for Sm3+ in the glass. The behaviour of Ω2 and Ω6 parameters suggested a decrease in the asymmetry degree of the local ligand field at Sm3+ sites and an increase in the covalency of Sm–O bond, respectively. This hypothesis was verified by analysing the structural role of Sm2O3 through Raman and infrared spectroscopy measurements." @default.
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- W2036420281 date "2000-09-01" @default.
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- W2036420281 title "Optical properties of Sm3+ doped lead fluoroborate glasses" @default.
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- W2036420281 doi "https://doi.org/10.1016/s0022-3697(00)00032-9" @default.
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