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• W2036422997 abstract "Phosphine substitution reactions between (η5-C5H5)Ru(PPh3)2Cl (1) and 1,2-bis(diphenylphosphino)ethane (Ph2P(CH2)2PPh2, dppe), in refluxing benzene or in toluene at 80°C afforded a mixture of complexes where dppe behaves both as a bridging and as a chelating ligand. CpRu(η2-dppe)Cl (2) and {[CpRu(Cl)]2(η2,μ2-dppe)2} (3) were separated by fractional precipitation from the reaction mother-liquor, and were characterized by 1H, 13C, 31P NMR, elemental analysis and IR spectroscopy. The (2):(3) ratio in the composition of the reaction product was found to be independent of the reaction time. In solution and at room temperature, (3) exists in both boat and chair conformers of a 10-membered ring, while at lower temperatures, and in the solid-state, only the chair conformer is observed. Compounds (2) and (3) undergo halide-displacement upon reacting with NaN3 in the presence of ethanol to yield CpRu(η2-dppe)(N3) (4) and {[CpRu(N3)]2(η2,μ2-dppe)2} (5), respectively. The crystal structures of (3) and (5) were determined." @default.
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• W2036422997 date "1999-09-01" @default.
• W2036422997 modified "2023-09-26" @default.
• W2036422997 title "Syntheses, characterization and structure determination of {[CpRu(X)]2(η2,μ2-dppe)2} complexes (X=Cl, N3; dppe=Ph2PCH2CH2PPh2)" @default.
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• W2036422997 doi "https://doi.org/10.1016/s0277-5387(99)00209-0" @default.
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