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- W2036423930 abstract "Proton magnetic resonance (PMR) spectra of NH 4 + ions bound to the cyclic antibiotics valinomycin and nonactin can be analyzed to give, unambiguously, information about the rotational correlation times, τ R , the Stokes' radii, r S , and the 14 N quadrupolar coupling constants, e 2 qQ/h, for the different complexes. For the NH 4 + -valinomycin complex: τ R = 3.2 × 10 −11 sec; r S = 4 × 10 −8 cm and e 2 qQ/h = 1.2MHz. For nonactin: τ R = 1.3 × 10 −10 sec; r S = 6 × 10 −8 cm and e 2 qQ/h = 0. It is also found that the proton chemical shift of the ion is 0.6 ppm to higher field when it is complexed to valinomycin as compared to nonactin." @default.
- W2036423930 created "2016-06-24" @default.
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- W2036423930 date "1975-04-01" @default.
- W2036423930 modified "2023-10-18" @default.
- W2036423930 title "Ammonium ion proton magnetic resonance probe of cation-binding, cyclic antibiotics" @default.
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- W2036423930 doi "https://doi.org/10.1016/s0006-291x(75)80452-9" @default.
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