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• W2036429461 abstract "A light in the dark: The fermentation products of the polyketide synthase CalE8 (without its cognate thioesterase) were identified and gave some insight into the elusive early steps of calicheamicin biosynthesis. Fermentation in either the light or dark resulted in different proportions of a new octaketide (see scheme) and led to an updated mechanistic proposal." @default.
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• W2036429461 date "2012-10-08" @default.
• W2036429461 modified "2023-10-18" @default.
• W2036429461 title "Environmental Control of the Calicheamicin Polyketide Synthase Leads to Detection of a Programmed Octaketide and a Proposal for Enediyne Biosynthesis" @default.
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• W2036429461 doi "https://doi.org/10.1002/anie.201206462" @default.
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