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- W2036475219 abstract "Chemical shift photoelectron diffraction has been applied to the model system of coadsorbed ${mathrm{PF}}_{mathit{x}}$(x=1,2,3) species on Ni(111), produced by electron beam fragmentation of a ${mathrm{PF}}_{3}$ overlayer, to determine quantitatively and independently the local adsorption site of each species. ${mathrm{PF}}_{3}$ is found to occupy atop adsorption sites above the outermost Ni layer atoms at a P-Ni bond length of (2.07ifmmodepmelsetextpmfi{}0.05) AA{}, ${mathrm{PF}}_{2}$ occupies bridge sites at a spacing of (1.70ifmmodepmelsetextpmfi{}0.05) AA{}, while the PF species occupy both types of threefold coordinated hollow sites, maintaining a constant P coordination throughout the fragmentation." @default.
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- W2036475219 date "1993-07-26" @default.
- W2036475219 modified "2023-10-18" @default.
- W2036475219 title "Structure determination for coadsorbed molecular fragments using chemical shift photoelectron diffraction" @default.
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- W2036475219 doi "https://doi.org/10.1103/physrevlett.71.581" @default.
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