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- W2036486345 abstract "The microwave specific effect(s) that can impact a microwave-assisted and photo-assisted reaction occurring on the surface of ZnO or TiO2 (P-25) particles was (were) examined by comparing the process occurring under rich magnetic field conditions and under magnetic/electric field conditions. The features of the photo-assisted process in the presence of microwaves rich in a magnetic field (H) and an electric field (E) are described on the basis of (i) the degradation dynamics of 4-chlorophenol (4-CP) at ambient temperatures, (ii) the number of OH radicals produced, and (iii) the dielectric properties of the metal oxides (in pellet form). For ZnO, the photoactivity is enhanced by a microwave specific non-thermal (i.e. non-caloric) effect originating from the microwaves’ magnetic field, but decreased by the thermal (i.e. caloric) factor originating from the microwaves’ electric field. Contrary to ZnO, the photoactivity of TiO2 (P-25) was enhanced by the synergistic effect between the magnetic and electric fields of the microwave radiation. Photocorrosion of ZnO in the aqueous dispersions was negligibly small (less than 0.05%) under UV, MW-EH, and UV/MW-EH irradiation conditions." @default.
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- W2036486345 date "2009-09-01" @default.
- W2036486345 modified "2023-09-25" @default.
- W2036486345 title "Characterization of microwave effects on metal-oxide materials: Zinc oxide and titanium dioxide" @default.
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- W2036486345 doi "https://doi.org/10.1016/j.apcatb.2009.06.008" @default.
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