FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036558426> ?p ?o ?g. }

• W2036558426 endingPage "2622" @default.
• W2036558426 startingPage "2615" @default.
• W2036558426 abstract "Abstract The coordination chemistry of dithiolene and diselenolene ligands towards the all‐selenium [Mo 3 Se 7 Br 6 ] 2– dianion has been investigated. Complexes ( n Bu 4 N) 2 [Zn(dmit) 2 ] (dmit = 1,3‐dithia‐2‐thioxo‐4,5‐dithiolate) and ( n Bu 4 N) 2 [Zn(dsit) 2 ] (dsit = 1,3‐dithia‐2‐thioxo‐4,5‐diselenolate) were employed as ligand precursors. The ( n Bu 4 N) 2 [Zn(dmit) 2 ] complex in acetonitrile at reflux showed unexpected reactivity with [Mo 3 Se 7 Br 6 ] 2– dianion in which the inner Se atoms were replaced by S (all but the μ 3 ‐Se atom) to afford a series of mixed chalcogen [Mo 3 Se 7– x S x (dmit) 3 ] 2– ( x = 0–6) dianions. Reaction of the [Mo 3 S 4 Se 3 Br 6 ] 2– dianion with ( n Bu 4 N) 2 [Zn(dmit) 2 ] under similar conditions also produced a mixed dmit‐containing cluster formulated as [Mo 3 S 7– x Se x (dmit) 3 ] 2– ( x = 0–3). The reactions were conveniently monitored by electrospray ionization mass spectrometry. The reactions of ( n Bu 4 N) 2 [Zn(dmit) 2 ] and ( n Bu 4 N) 2 [Zn(dsit) 2 ] with the [Mo 3 Se 7 Br 6 ] 2– dianion in dichloromethane at room temperature prevented chalcogen scrambling and allowed us to isolate the cluster salts ( n Bu 4 N) 2 [Mo 3 Se 7 (dmit) 3 ] {( n Bu 4 N) 2 [ 1 ]} and ( n Bu 4 N) 2 [Mo 3 Se 7 (dsit) 3 ] {( n Bu 4 N) 2 [ 2 ]} in analytically pure form. The crystallization of ( n Bu 4 N) 2 [ 1 ] from dichloromethane/diethyl ether resulted in ( n Bu 4 N) 2 [Mo 3 Se 6.1 S 0.9 (dmit) 3 ] with partial substitution of the Se eq atoms in the cluster core. The crystal structure of ( n Bu 4 N) 2 [Mo 3 Se 6.1 S 0.9 (dmit) 3 ] was determined by single‐crystal X‐ray analysis. Dianionic complexes ( n Bu 4 N) 2 [ 1 ], ( n Bu 4 N) 2 [ 2 ], and ( n Bu 4 N) 2 [Mo 3 Se 7– x S x (dmit) 3 ] ( x = 0–6) were partially oxidized by iodine to afford dark semiconducting powders. These solids exhibit moderate electrical conductivities (7 × 10 –2 to 6 × 10 –3 S cm –1 ) and present antiferromagnetic exchange interactions and therefore represent new examples of magnetic Mo 3 Q 7 ‐based single‐component conductors." @default.
• W2036558426 created "2016-06-24" @default.
• W2036558426 creator A5013127387 @default.
• W2036558426 creator A5038678975 @default.
• W2036558426 creator A5038723646 @default.
• W2036558426 creator A5059864719 @default.
• W2036558426 creator A5076287048 @default.
• W2036558426 date "2013-03-18" @default.
• W2036558426 modified "2023-10-17" @default.
• W2036558426 title "Mo ₃ Q ₇ (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single‐Component Molecular Conductors" @default.
• W2036558426 cites W1974518943 @default.
• W2036558426 cites W1975918439 @default.
• W2036558426 cites W1980647937 @default.
• W2036558426 cites W1982201073 @default.
• W2036558426 cites W1984237630 @default.
• W2036558426 cites W1987881689 @default.
• W2036558426 cites W1995403643 @default.
• W2036558426 cites W2016533186 @default.
• W2036558426 cites W2017001389 @default.
• W2036558426 cites W2051188308 @default.
• W2036558426 cites W2055013611 @default.
• W2036558426 cites W2055330287 @default.
• W2036558426 cites W2060934583 @default.
• W2036558426 cites W2063443513 @default.
• W2036558426 cites W2063793986 @default.
• W2036558426 cites W2085362680 @default.
• W2036558426 cites W2085574416 @default.
• W2036558426 cites W2089567858 @default.
• W2036558426 cites W2099092586 @default.
• W2036558426 cites W2161786653 @default.
• W2036558426 cites W2312826701 @default.
• W2036558426 cites W2950299723 @default.
• W2036558426 cites W2950391552 @default.
• W2036558426 cites W2950846368 @default.
• W2036558426 cites W2951703643 @default.
• W2036558426 cites W4232764647 @default.
• W2036558426 doi "https://doi.org/10.1002/ejic.201201532" @default.
• W2036558426 hasPublicationYear "2013" @default.
• W2036558426 type Work @default.
• W2036558426 sameAs 2036558426 @default.
• W2036558426 citedByCount "31" @default.
• W2036558426 countsByYear W20365584262014 @default.
• W2036558426 countsByYear W20365584262015 @default.
• W2036558426 countsByYear W20365584262016 @default.
• W2036558426 countsByYear W20365584262017 @default.
• W2036558426 countsByYear W20365584262018 @default.
• W2036558426 countsByYear W20365584262019 @default.
• W2036558426 countsByYear W20365584262020 @default.
• W2036558426 countsByYear W20365584262021 @default.
• W2036558426 countsByYear W20365584262022 @default.
• W2036558426 countsByYear W20365584262023 @default.
• W2036558426 crossrefType "journal-article" @default.
• W2036558426 hasAuthorship W2036558426A5013127387 @default.
• W2036558426 hasAuthorship W2036558426A5038678975 @default.
• W2036558426 hasAuthorship W2036558426A5038723646 @default.
• W2036558426 hasAuthorship W2036558426A5059864719 @default.
• W2036558426 hasAuthorship W2036558426A5076287048 @default.
• W2036558426 hasConcept C116569031 @default.
• W2036558426 hasConcept C142724271 @default.
• W2036558426 hasConcept C155647269 @default.
• W2036558426 hasConcept C158733187 @default.
• W2036558426 hasConcept C162356407 @default.
• W2036558426 hasConcept C164866538 @default.
• W2036558426 hasConcept C170493617 @default.
• W2036558426 hasConcept C178790620 @default.
• W2036558426 hasConcept C185592680 @default.
• W2036558426 hasConcept C199033913 @default.
• W2036558426 hasConcept C199360897 @default.
• W2036558426 hasConcept C204787440 @default.
• W2036558426 hasConcept C2776910235 @default.
• W2036558426 hasConcept C2777463227 @default.
• W2036558426 hasConcept C2780400988 @default.
• W2036558426 hasConcept C2780471494 @default.
• W2036558426 hasConcept C40684141 @default.
• W2036558426 hasConcept C41008148 @default.
• W2036558426 hasConcept C43617362 @default.
• W2036558426 hasConcept C553756173 @default.
• W2036558426 hasConcept C55493867 @default.
• W2036558426 hasConcept C71240020 @default.
• W2036558426 hasConcept C71924100 @default.
• W2036558426 hasConcept C8010536 @default.
• W2036558426 hasConceptScore W2036558426C116569031 @default.
• W2036558426 hasConceptScore W2036558426C142724271 @default.
• W2036558426 hasConceptScore W2036558426C155647269 @default.
• W2036558426 hasConceptScore W2036558426C158733187 @default.
• W2036558426 hasConceptScore W2036558426C162356407 @default.
• W2036558426 hasConceptScore W2036558426C164866538 @default.
• W2036558426 hasConceptScore W2036558426C170493617 @default.
• W2036558426 hasConceptScore W2036558426C178790620 @default.
• W2036558426 hasConceptScore W2036558426C185592680 @default.
• W2036558426 hasConceptScore W2036558426C199033913 @default.
• W2036558426 hasConceptScore W2036558426C199360897 @default.
• W2036558426 hasConceptScore W2036558426C204787440 @default.
• W2036558426 hasConceptScore W2036558426C2776910235 @default.
• W2036558426 hasConceptScore W2036558426C2777463227 @default.
• W2036558426 hasConceptScore W2036558426C2780400988 @default.
• W2036558426 hasConceptScore W2036558426C2780471494 @default.
• W2036558426 hasConceptScore W2036558426C40684141 @default.

• next