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- W2036571806 abstract "Die in einer Auswahl anionischer Systeme hergestellten Acrylnitrilpolymere weisen verzweigte Strukturen auf, die auf durch den polaren Charakter des Monomers bedingte Nebenreaktionen zurückzuführen sind. Die daraus resultierende Zunahme der Polymerknäueldichte konnte experimentell über verschiedene Kriterien ([η]-M-Beziehung, Huggins-Konstante, Kontraktionsfaktor) nachgewiesen werden. Polyacrylonitrile samples obtained in different anionic systems contain branched structures the formation of which is explained by secondary reactions caused by the polarity of the monomer. The increase in density of the polmer coils resulting from branching was demonstrated experimentally by using different criteria ([η]-M relationship, Huggins constant, contraction factor)." @default.
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- W2036571806 date "1981-12-01" @default.
- W2036571806 modified "2023-10-18" @default.
- W2036571806 title "Beiträge zum Mechanismus der anionisch initiierten Acrylnitrilpolymerisation. I. Zur Kenntnis von Verzweigungsreaktionen" @default.
- W2036571806 doi "https://doi.org/10.1002/actp.1981.010321206" @default.
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