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- W2036601716 abstract "Two approaches to the strigolactone tricyclic lactone skeleton 2 were investigated using ketene/ketene-iminium cycloaddition to olefins. Finally, the first enantioselective access to the four stereoisomers of 5-deoxystrigol 1 is reported using an intramolecular [2+2] cycloaddition of homochiral ketene-iminium salts 5. Very high asymmetric control was achieved with C-2 symmetric pyrrolidines as chiral auxiliary." @default.
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- W2036601716 date "2014-11-01" @default.
- W2036601716 modified "2023-09-30" @default.
- W2036601716 title "Asymmetric synthesis of the four stereoisomers of 5-deoxystrigol" @default.
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- W2036601716 doi "https://doi.org/10.1016/j.tetlet.2014.10.040" @default.
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