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- W2036605242 abstract "A highly torquoselective olefination of alkynoates to provide functionalized tetrasubstituted olefins, (E)-2-en-4-ynoic acids, is described. Addition of Brønsted acids dramatically switched the mode of the Ag(I)-catalyzed cyclization of the resulting enyne carboxylic acids to give either tetronic acids or 2-pyrones." @default.
- W2036605242 created "2016-06-24" @default.
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- W2036605242 date "2009-11-04" @default.
- W2036605242 modified "2023-10-18" @default.
- W2036605242 title "Stereoselective Synthesis of (<i>E</i>)-2-En-4-ynoic Acids with Ynolates: Catalytic Conversion to Tetronic Acids and 2-Pyrones" @default.
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- W2036605242 doi "https://doi.org/10.1021/ol902086t" @default.
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