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• W2036620263 endingPage "11105" @default.
• W2036620263 startingPage "11100" @default.
• W2036620263 abstract "The activity coefficients at infinite dilution, gamma 13 (infinity) for 32 solutes: alkanes, alkenes, alkynes, cycloalkanes, aromatic hydrocarbons, alcohols, thiophene, tetrahydrofurane, tert-butyl methyl ether, and water in the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate [BMIM][CF3SO3] were determined by gas-liquid chromatography at the temperatures from 298.15 to 368.15 K. The partial molar excess enthalpies at infinite dilution values Delta H 1 (E,infinity) were calculated from the experimental gamma 13 (infinity) values obtained over the temperature range. The selectivities for the hexane/benzene, cyclohexane/benzene, n-hexane/thiophene, n-decane/thiophene, cyclohexane/thiophene, toluene/thiophene, and oct-1-ene/thiophene separation problems were calculated from the gamma 13 (infinity). Obtained values were compared to the literature values for the other ionic liquids, NMP, and sulfolane." @default.
• W2036620263 created "2016-06-24" @default.
• W2036620263 creator A5017577532 @default.
• W2036620263 creator A5049227096 @default.
• W2036620263 date "2008-08-09" @default.
• W2036620263 modified "2023-09-26" @default.
• W2036620263 title "Activity Coefficients at Infinite Dilution Measurements for Organic Solutes and Water in the Ionic Liquid 1-Butyl-3-methylimidazolium Trifluoromethanesulfonate" @default.
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• W2036620263 doi "https://doi.org/10.1021/jp804107y" @default.
• W2036620263 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18693694" @default.
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