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- W2036631242 abstract "Die Strukturen der Titelverbindungen wurden aus Diffraktometer-Einkristalldaten (gemessen bei −130°C) bestimmt und zu ungewichteten R-Werten von 0.034 für (R3SiN)3S )(1) und 0.047 für (R3CN)3S (2)verfeinert. 2 kristallisiert triklin, P1. Und 1 hexagonal, P63/m. In beiden Strukturen wird eine trigonal planare Koordination des zentralen Schwefelatoms beobachtet, doch deuten die relativ großen Koeffizienten der anisotropen Temperaturfaktoren senkrecht zu den SN3-Ebenen in 1 und 2 auf eine Fehlordnung als Folge geringer Abweichungen von der Planarität in den einzelnen Molekülen hin. Die SN-Abstände betragen 150.4 pm (1) und 151.5 pm (2, Mittelwert). Planar Threefold Coordination of Sulfur(VI): Crystal and Molecular Structures of (R3SiN)3S and (R3CN)3S (RCH3) at −130°C The crystal structures of the title compounds were determined from single crystal X-ray data (measured at −130°C) and refined to unweighted R-values of 0.034 for (R3SiN)3S (1) and 0.047 for (R3CN)3S(2). 2 crystallizes in the triclinic space group P1 and 1 in the hexagonal space group P63/m. Both structures exhibit a planar threefold nitrogen coordination of the sulfur but the large coefficients of the temperature factors perpendicular to the SN3 planes in 1 and 2 might indicate a disorder due to small deviations from planarity. The SN bond lengths were found to be 150.4 (1) and 151.5 pm (2, mean)." @default.
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- W2036631242 date "1979-05-01" @default.
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- W2036631242 title "Trigonal planar koordinierter Schwefel(VI): Die Kristall‐ und Molekülstrukturen von (R <sub>3</sub> SiN) <sub>3</sub> S und (R <sub>3</sub> CN) <sub>3</sub> S (RCH <sub>3</sub> ) bei −130°C" @default.
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- W2036631242 doi "https://doi.org/10.1002/cber.19791120525" @default.
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