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• W2036662966 endingPage "1738" @default.
• W2036662966 startingPage "1734" @default.
• W2036662966 abstract "Reaction of 2 equiv of the previously reported germolyl anion Li[C4Me4GeSi(SiMe3)3] with FeCl2(THT)1.5 (THT = tetrahydrothiophene) at low temperature gave the new bis-η5-germolyl complex [η5-C4Me4GeSi(SiMe3)3]2Fe (1), which was characterized by X-ray crystallography. Reaction of 1 with I2 resulted in loss of the germolyl ligand as C4Me4Ge(I)[Si(SiMe3)3], while the reaction with MeLi produced the ferrocenophane ansa-(Me3Si)2Si(η5-GeC4Me4)2Fe (4). X-ray crystallographic analysis of this compound revealed that the Ge atoms are displaced significantly out of the C4 plane. Attempts to induce the ring-opening polymerization of 4 were unsuccessful." @default.
• W2036662966 created "2016-06-24" @default.
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• W2036662966 date "2002-03-21" @default.
• W2036662966 modified "2023-10-14" @default.
• W2036662966 title "Synthesis and Reactivity of η⁵-Germacyclopentadienyl Complexes of Iron" @default.
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• W2036662966 doi "https://doi.org/10.1021/om0110991" @default.
• W2036662966 hasPublicationYear "2002" @default.
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