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• W2036680377 abstract "Abstract The solvothermal reaction of Zn(NO3)2·6H2O with 1,4-naphthalenedicarboxylic (1,4-H2ndc) and 3,3′-dimethyl-4,4′-bipyridine (dmbpy) generates a new twofold-interpenetrating 3D zinc–organic framework, [Zn2(1,4-ndc)2(dmbpy)]n, (1). Two adjacent ZnII atoms form a paddle-wheel Zn2(COO)4 secondary building unit (SBU), which is linked by 1,4-ndc linkers with bis(syn, syn-bridging bidentate) bonding modes within the layer to form a 2D net and is further pillared by dmbpy struts to give rise to a 3D framework with channels of 6.7 × 6.7 A2. PXRD shows that complex 1 was stable in air after moisture exposure for 30 days. 1 emits the intense indigotin photoluminescence at room temperature. Moreover, 1 has a remarkable activity for degradation of methyl orange in a photo-assisted Fenton-like process." @default.
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• W2036680377 date "2015-03-01" @default.
• W2036680377 modified "2023-09-25" @default.
• W2036680377 title "Improving the moisture stability of a 3D zinc–organic framework by incorporating methyl groups into the auxiliary ligand: Synthesis, characterization, luminescence and catalytic properties" @default.
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• W2036680377 doi "https://doi.org/10.1016/j.molstruc.2014.11.005" @default.
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