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- W2036690927 abstract "Des Alkylmagnésiens primaires ont été préparés dans des diluants hydrocarbonés tels que le benzène et le toluène en présence d'un équivalent diéthyléther ou de tétrahydrofuranne et sont utilisés dans les réactions sur la diisopropylcétone et sur la cyclohexylisopropylcétone. Les résultats de ces réactions éthérées montrent que la réaction d'addition est fortement favorisée au détriment de la réaction de réduction. Ils montrent aussi qu'il n'y a pas de différences importantes dans la distribution des produits réactionnels lorsqu'on remplace l'éther par le tétrahydrofuranne et le benzène par le toluène. Primary alkylmagnesium bromides are prepared in hydrocarbon solutions such as benzene or toluene using 1 equivalent of diethyl ether or tetrahydrofuran. Their reactions with diisopropylketone and cyclohexylisopropylketone increase drastically the addition products in comparison with the reactions in diethyl ether or in tetrahydrofuran. No important differences were found in the distribution of reaction products between diethylether or tetrahydrofuran and between benzene and toluene when they are used as complexant and diluent respectively." @default.
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- W2036690927 date "1982-01-01" @default.
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- W2036690927 title "Etude de l'influence du diluant hydrocarbone dans la reaction des organomagnesiens primaires sur les cetones encombrees" @default.
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- W2036690927 doi "https://doi.org/10.1016/0040-4020(82)80061-6" @default.
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