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- W2036691517 abstract "Modern methods of analysis have been used to calculate the molecular parameters contained in the Patterson equation which describes the state of phase of the cellulose acetate (CA) solutions; the Prigogine-Patterson theory has been employed. A dependence of the reduced critical temperatures on the molecular weight of the polymer has been found, but the experimental values disagree with the theoritical. The latter is explained by the presence of structuration and the initiation of the polymer phase, both of which appear long before the phase separation. The temperature dependences of the chemical and structural parameters c1ν2 and c1τ2 have been calculated and their differing contributions to ξ1 are shown. The lower limit of the solubilization temperature of the system cellulose triacetate-methylene chloride which had not been detected experimentally, has been predicted on the basis of the main points of the theory." @default.
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- W2036691517 date "1978-01-01" @default.
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- W2036691517 title "Thermodynamic study of the phase equilibrium of cellulose acetate solutions in the light of the prigogine-patterson theory" @default.
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- W2036691517 doi "https://doi.org/10.1016/0032-3950(78)90353-2" @default.
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