Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036698232> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2036698232 endingPage "284" @default.
- W2036698232 startingPage "273" @default.
- W2036698232 abstract "Supported mixed bidentate rhodium and iridium complexes derived from phosphonate-phosphanes were studied in the methanol carbonylation and in the hydroformylations of ethylene and propylene. Heterobidentate complexes of rhodium showed higher activities than rhodium bisphosphane complexes in homogeneous and vapour-phase methanol carbonylation. The hemilabile behaviour of the mixed bidentate complexes may explain these findings. In ethylene hydroformylation, supported phosphonate-phosphane Rh-complexes did not show higher activities than supported rhodium-bisphosphane complexes. However, phosphonate-phosphane ligands suppressed the undesired ethane formation in this reaction. Excellent rhodium catalysts for vapour-phase carbonylations were obtained, when Rh phosphane complexes were anchored in lamellar zirconium phosphonate structures with mixed phosphonate anions. These catalysts were several times more active than rhodium supported on silica or on activated carbon, showed a superior stability, and produced butyraldehydes with up to 98% chemoselectivity in the vapour-phase hydroformylation of propylene." @default.
- W2036698232 created "2016-06-24" @default.
- W2036698232 creator A5030358040 @default.
- W2036698232 creator A5034009185 @default.
- W2036698232 creator A5034066835 @default.
- W2036698232 creator A5035216567 @default.
- W2036698232 creator A5066041498 @default.
- W2036698232 date "1997-06-01" @default.
- W2036698232 modified "2023-09-24" @default.
- W2036698232 title "Supported phosphonate-phosphane complexes for vapour-phase carbonylation" @default.
- W2036698232 cites W1560701292 @default.
- W2036698232 cites W1972827142 @default.
- W2036698232 cites W1980895408 @default.
- W2036698232 cites W1983848736 @default.
- W2036698232 cites W1991663245 @default.
- W2036698232 cites W1993680333 @default.
- W2036698232 cites W2000516556 @default.
- W2036698232 cites W2009276809 @default.
- W2036698232 cites W2038358766 @default.
- W2036698232 cites W2051444371 @default.
- W2036698232 cites W2055231254 @default.
- W2036698232 cites W2058244145 @default.
- W2036698232 cites W2064320953 @default.
- W2036698232 cites W2074160912 @default.
- W2036698232 cites W2074161972 @default.
- W2036698232 cites W2079976944 @default.
- W2036698232 cites W2080322255 @default.
- W2036698232 cites W2084247959 @default.
- W2036698232 cites W2088654577 @default.
- W2036698232 cites W2092174428 @default.
- W2036698232 cites W2134913810 @default.
- W2036698232 cites W246236883 @default.
- W2036698232 cites W4235639095 @default.
- W2036698232 cites W2063447281 @default.
- W2036698232 doi "https://doi.org/10.1016/s0920-5861(96)00228-3" @default.
- W2036698232 hasPublicationYear "1997" @default.
- W2036698232 type Work @default.
- W2036698232 sameAs 2036698232 @default.
- W2036698232 citedByCount "16" @default.
- W2036698232 countsByYear W20366982322016 @default.
- W2036698232 crossrefType "journal-article" @default.
- W2036698232 hasAuthorship W2036698232A5030358040 @default.
- W2036698232 hasAuthorship W2036698232A5034009185 @default.
- W2036698232 hasAuthorship W2036698232A5034066835 @default.
- W2036698232 hasAuthorship W2036698232A5035216567 @default.
- W2036698232 hasAuthorship W2036698232A5066041498 @default.
- W2036698232 hasConcept C100805817 @default.
- W2036698232 hasConcept C155647269 @default.
- W2036698232 hasConcept C161790260 @default.
- W2036698232 hasConcept C168382676 @default.
- W2036698232 hasConcept C178516000 @default.
- W2036698232 hasConcept C178790620 @default.
- W2036698232 hasConcept C185592680 @default.
- W2036698232 hasConcept C188027245 @default.
- W2036698232 hasConcept C190667039 @default.
- W2036698232 hasConcept C2776254738 @default.
- W2036698232 hasConcept C2777626080 @default.
- W2036698232 hasConcept C2778597550 @default.
- W2036698232 hasConcept C2779607525 @default.
- W2036698232 hasConcept C512735826 @default.
- W2036698232 hasConcept C521398313 @default.
- W2036698232 hasConcept C544153396 @default.
- W2036698232 hasConceptScore W2036698232C100805817 @default.
- W2036698232 hasConceptScore W2036698232C155647269 @default.
- W2036698232 hasConceptScore W2036698232C161790260 @default.
- W2036698232 hasConceptScore W2036698232C168382676 @default.
- W2036698232 hasConceptScore W2036698232C178516000 @default.
- W2036698232 hasConceptScore W2036698232C178790620 @default.
- W2036698232 hasConceptScore W2036698232C185592680 @default.
- W2036698232 hasConceptScore W2036698232C188027245 @default.
- W2036698232 hasConceptScore W2036698232C190667039 @default.
- W2036698232 hasConceptScore W2036698232C2776254738 @default.
- W2036698232 hasConceptScore W2036698232C2777626080 @default.
- W2036698232 hasConceptScore W2036698232C2778597550 @default.
- W2036698232 hasConceptScore W2036698232C2779607525 @default.
- W2036698232 hasConceptScore W2036698232C512735826 @default.
- W2036698232 hasConceptScore W2036698232C521398313 @default.
- W2036698232 hasConceptScore W2036698232C544153396 @default.
- W2036698232 hasIssue "3" @default.
- W2036698232 hasLocation W20366982321 @default.
- W2036698232 hasOpenAccess W2036698232 @default.
- W2036698232 hasPrimaryLocation W20366982321 @default.
- W2036698232 hasRelatedWork W141696071 @default.
- W2036698232 hasRelatedWork W1980883813 @default.
- W2036698232 hasRelatedWork W2002831340 @default.
- W2036698232 hasRelatedWork W2036698232 @default.
- W2036698232 hasRelatedWork W2038282030 @default.
- W2036698232 hasRelatedWork W2039567115 @default.
- W2036698232 hasRelatedWork W2067038107 @default.
- W2036698232 hasRelatedWork W2088393300 @default.
- W2036698232 hasRelatedWork W2132010819 @default.
- W2036698232 hasRelatedWork W4244986460 @default.
- W2036698232 hasVolume "36" @default.
- W2036698232 isParatext "false" @default.
- W2036698232 isRetracted "false" @default.
- W2036698232 magId "2036698232" @default.
- W2036698232 workType "article" @default.