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- W2036699840 abstract "A series of heterobimetallic xenophilic complexes containing an unsupported polar metal−metal bond, TpiPr2M-Co(CO)4 (M = Ni, Co, Fe, Mn), is synthesized by treatment of the labile cationic species [TpiPr2M(NCMe)3]+ with PPN[Co(CO)4], and the polar nature of the metal−metal bond is characterized by spectroscopic and crystallographic methods as well as by the reaction with MeCN, causing metal−metal bond heterolysis to give the ion pairs [TpiPr2M(NCMe)3]+[Co(CO)4]-." @default.
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- W2036699840 date "2001-10-25" @default.
- W2036699840 modified "2023-10-03" @default.
- W2036699840 title "Rational Synthesis and Reversible Metal−Metal Bond Scission of Heterobimetallic Xenophilic Complexes Containing an Unsupported, Polar Metal−Metal Bond, Tp<sup>i</sup><sup>Pr</sup><sub><sup>2</sup></sub>M−Co(CO)<sub>3</sub>L (M = Ni, Co, Fe, Mn; L = CO, PPh<sub>3</sub>)" @default.
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- W2036699840 doi "https://doi.org/10.1021/om010651j" @default.
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