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• W2036700232 abstract "The system K1+xTa1+xW1−xO6 · nH2O, 0 <x< 1, has been investigated by means of TG, X-ray diffraction and impedance measurements in the temperature region 300–700 K. The samples possess the cubic pyrochlore structure over the entire compositional and temperature range studied. The largest ionic conductivity is found for composition x = 0.6, n = 0; σ = 0.96·10−3 (ω cm)−1 at 675 K. The In(σT), In(σ0) and Ea versus x curves exhibit a discontinuity between x = 0.5 and 0.6. The compositional dependence of the ionic conductivity and In(σ0) is correlated to the distribution of K+ ions at the crystallographic lattice sites 8b and 16d. The samples contain absorbed water which is lost on heating and fully regained on subsequent cooling. The water content at room temperature is approximately equal to n = 1 for all x." @default.
• W2036700232 created "2016-06-24" @default.
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• W2036700232 date "1980-01-01" @default.
• W2036700232 modified "2023-10-03" @default.
• W2036700232 title "Studies on composition, structure and ionic conductivity of the pyrochlore type system ," @default.
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• W2036700232 doi "https://doi.org/10.1016/0025-5408(80)90159-2" @default.
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