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- W2036700916 abstract "The pK a values often substituted primary anilines and six substituted tertiary anilines have been determined in 70% DMSO–water. The ΔpK a values relative to those in aqueous solution indicate that DMSO is about 2 log units stronger as a base than H 2 O. The normal order of basicity (tertiary > primary) is inverted in this solvent system and the Hammett ρ values for the two series provide evidence for a different ionization mechanism than that in water." @default.
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- W2036700916 date "1972-02-15" @default.
- W2036700916 modified "2023-09-26" @default.
- W2036700916 title "The Dissociation of Anilinium Ions in Aqueous Dimethylsulfoxide" @default.
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- W2036700916 doi "https://doi.org/10.1139/v72-073" @default.
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