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- W2036700943 abstract "Abstract The reaction of the nona-osmium cluster dianion [(Ph3P)2N]2[Os9(CO)24] with the electrophilic gold reagents “AuPR + 3 ” and “Au2L2+” (where R=Ph (2a, 3a), Cy (2b, 3b) and L=bis-(diphenylphosphino)methane (DPPM) (1a) or 1,2-bis-(diphenyl)ethane (DPPE) (1b)) has been studied. The monogold fragment reacts to give both the mono- and di-substituted products [(Ph3P)2N][Os9(CO)24{Au(PR3)}] and [Os9(CO)24{Au(PR3)}2]. The structure of the latter cluster (R=Cy (2b)) has been determined by a single crystal X-ray diffraction analysis and a major rearrangement of the metal core geometry was found to have occurred on coordination of the gold fragments. In contrast, reaction with the digold reagent “Au2L2+” results in the isolation of only one product of formulation [Os9(CO)23(Au2L)], where coordination of the heteroatom moiety has been accompanied with the loss of a carbonyl ligand. From a single crystal X-ray diffraction analysis (L=DPPE (1b)) this compound was shown to have retained its original cluster geometry, with the gold atoms coordinated in close proximity to each other." @default.
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- W2036700943 date "1998-01-01" @default.
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- W2036700943 title "Metal core rearrangements in hetero-bimetallic nona-osmium carbonyl clusters; the crystal and molecular structures of [Os9(CO)24{Au(PCy3)}2] and [Os9(CO)23(Au2DPPE)]1Dedicated to Professor Ken Wade on the occasion of his 65th birthday in recognition of his outstanding contributions to organometallic and inorganic chemistry.1" @default.
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- W2036700943 doi "https://doi.org/10.1016/s0022-328x(97)00188-5" @default.
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