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- W2036702442 abstract "Exchange and oxidation of C16O were investigated at 450°C on 18O-predosed Rh and Pt catalysts supported on A12O3, CeO2 and CeO2-Al2O3. In all cases, a rapid exchange of C16O with the surface can be observed. CO oxidation leads to C16O2, C16O18O and C18O2. Significant formation of C16O2 is due to the relatively high 16O coverage in reaction resulting from the C16O exchange and from an exchange between O surface species and 16O internal atoms. Hydrogen is also formed via a water-gas shift reaction (CO + surface OH) in higher proportion on CeO2-containing catalysts than on A12O3. Chlorine inhibits all the reactions (exchange, oxidation and WGS) and particularly the internal exchange." @default.
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- W2036702442 date "1996-05-01" @default.
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- W2036702442 title "Exchange and oxidation of C16O on 18O-predosed RhAl2O3 and RhCeO2 catalysts" @default.
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- W2036702442 doi "https://doi.org/10.1016/0920-5861(95)00274-x" @default.
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