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- W2036702505 abstract "Der Butadien(tricarbonyl)eisen‐Komplex (−)‐1 kann mit dem Allenylsilan 2 nahezu diastereospezifisch ( de ≥98%) zum (CO) 3 Fe‐geschützten Homopropargylalkohol 3 umgesetzt werden (Ausb. 65%). Die Dreifachbindung in 3 läßt sich stereospezifisch zu einer cis‐Doppelbindung reduzieren. Dekomplexierung des Produktes oder direkt von 3 liefern Schlüsselzwischenprodukte für die Synthese von Leukotrien B 4 bzw. 14,15‐Didehydroleukotrien B 4 . magnified image" @default.
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- W2036702505 date "1988-09-01" @default.
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- W2036702505 title "Kurze, hochenantioselektive Synthese einer Schlüsselverbindung zur Herstellung von Leukotrien B4 und dessen 14,15-Didehydro-Derivat" @default.
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- W2036702505 doi "https://doi.org/10.1002/ange.19881000929" @default.
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