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- W2036718959 abstract "The first diastereoselective synthesis of l-xylo-(2R,3S,4S)-C18-phytosphingosine (1) has been achieved by double stereodifferentiation of enantiomerically enriched terminal olefin 14 using (DHQD)2–PHAL ligand in an asymmetric dihydroxylation with a diastereomeric ratio of 83:17. This phytosphingosine was fully characterized by the physical and spectral data of the corresponding tetraacetate 21." @default.
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- W2036718959 date "2000-12-01" @default.
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- W2036718959 title "Double stereodifferentiation in asymmetric dihydroxylation: application to the first diastereoselective synthesis of l-xylo-[2R,3S,4S]-C18-phytosphingosine" @default.
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- W2036718959 doi "https://doi.org/10.1016/s0040-4039(00)01851-7" @default.
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