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• W2036742888 endingPage "1184" @default.
• W2036742888 startingPage "1175" @default.
• W2036742888 abstract "Fluorine-containing heterocyclic and carbocyclic compounds attract widespread attention as important components of agrochemicals, pharmaceuticals, materials, and catalysts. To provide a general route to these compounds, we have developed a new methodology to construct fluorocarbon-bearing cyclic systems based on ring closure of functionalized 2-trifluoromethyl-1-alkenes, readily obtained from commercially available CH2=C(CF3)Br or CF3CO2Et. Their intramolecular reactions, such as nucleophilic substitution or addition, alkene insertion, and electrocyclization, provide a wide variety of five- and six-membered heterocycles and carbocycles bearing a fluorinated one-carbon unit (a =CF2, CHF2, or CF3 group). To construct five-membered rings, we successfully accomplished a nucleophilic 5-endo-trig cyclization and 5-endo alkene insertion, normally disfavored processes, as well as fluorine-directed Nazarov cyclization." @default.
• W2036742888 created "2016-06-24" @default.
• W2036742888 creator A5030722990 @default.
• W2036742888 date "2010-01-01" @default.
• W2036742888 modified "2023-10-03" @default.
• W2036742888 title "Synthetic Methods for Heterocycles and Carbocycles Bearing Fluorinated One-Carbon Units (=CF₂, CHF₂, or CF₃): Intramolecular Reaction of 2-Trifluoromethyl-1-alkenes" @default.
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