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- W2036748101 abstract "We present $mathrm{C}phantom{rule{0.2em}{0ex}}1s$ x-ray absorption, x-ray emission, and resonant inelastic x-ray scattering (RIXS) spectra of single-phase crystalline ${mathrm{K}}_{3}{mathrm{C}}_{60}$. The comparison to valence-band photoelectron spectra from the same sample facilitates identification of the contribution from surface and bulk electronic states in the latter. Bulk-sensitive techniques show that the valence bands of ${mathrm{K}}_{3}{mathrm{C}}_{60}$ and pure ${mathrm{C}}_{60}$ are characterized by spectral features of similar width, in agreement with the predictions of band-structure calculations. Symmetry selectivity in the RIXS process allows us to assign peaks in the $mathrm{C}phantom{rule{0.2em}{0ex}}1s$ absorption spectrum, demonstrating a close correspondence with pure ${mathrm{C}}_{60}$ also in the conduction band. The symmetry selectivity is as pronounced in ${mathrm{K}}_{3}{mathrm{C}}_{60}$ as in pure ${mathrm{C}}_{60}$, indicating that the local ${mathrm{C}}_{60}$ symmetry is not appreciably affected by the K doping, either in the ground state or intermediate state, on the time scale of $6phantom{rule{0.3em}{0ex}}mathrm{fs}$." @default.
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- W2036748101 date "2007-05-22" @default.
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- W2036748101 title "Bulk electronic structure of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>K</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>C</mml:mi><mml:mn>60</mml:mn></mml:msub></mml:mrow></mml:math>as revealed by soft x-rays" @default.
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- W2036748101 doi "https://doi.org/10.1103/physrevb.75.195432" @default.
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