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- W2036764579 abstract "Abstract The potentiometric response characteristics of a copper metal indicator electrode are reported in a flow-injection system when metal ions are injected into ligands of differing complexing strengths in buffered carrier streams. Theoretical Nernstian derivation of equations relating peak heights to both the injected metal ion concentration and the ligand concentration are shown to give good agreement with experimental peak height measurements for Ca 2+ , Al 3+ , Pb 2+ , Cd 2+ , Co 2+ , Cu 2+ , Ni 2+ , Mn 2+ , Zn 2+ and UO 2+ 2 . A study of injections into buffered ligand streams containing EDTA, ethylenediamine, triethylenetetramine, iminodiacetate, citrate, or glutamate shows advantages for the use of the more weakly complexing ligands in the carrier stream. Linear response are obtained at low (10 −3 –10 −4 M) metal ion concentrations over narrow ranges. Some chromatographic applications are outlined." @default.
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- W2036764579 date "1985-01-01" @default.
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- W2036764579 title "Response characteristics of a potentiometric detector with a copper metal electrode for flow-injection and chromatographic determinations of metal ions" @default.
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