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- W2036764845 abstract "Rotational, spin‐orbit, lambda doublet, and kinetic energy distributions were measured by laser‐excited fluorescence techniques for the nitric oxide fragments formed from the vibrational predissociation of nitric oxide dimers in a free jet expansion. The NO fragments, produced following excitation in the dimer ν1 fundamental, were described by a rotational ‘‘temperature’’ of TR≂100 K, with full equilibration of lambda doublet states, and approximately equal populations in the two spin‐orbit states. The velocity distributions were isotropic with an average fragment kinetic energy of 400 cm−1. Time‐resolved measurements placed a 15 ns upper limit on the predissociation lifetime." @default.
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- W2036764845 date "1986-08-15" @default.
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- W2036764845 title "Vibrational predissociation of the nitric oxide dimer: Total energy distribution in the fragments" @default.
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- W2036764845 doi "https://doi.org/10.1063/1.451082" @default.
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