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• W2036865212 startingPage "11613" @default.
• W2036865212 abstract "A hydrogen bond formed between the superoxide anion and the ammonium ion (NH4+) accelerates electron transfer from the C60 radical anion to oxygen significantly, whereas the tetra-n-butylammonium ion has no ability to form a hydrogen bond with the superoxidie anion, exhibiting no acceleration of the electron-transfer reduction of oxygen. The second-order rate constant of electron transfer from C60•- to O2 increases linearly with increasing concentration of NH4+. This indicates that O2•- produced in the electron transfer from C60 to O2 is stabilized by 1:1 complex formation between O2•- and NH4+. The 1:1 complex formed between O2•- and NH4+ was detected by ESR. The binding of O2•- with NH4+ results in a positive shift of the reduction potential of O2 with increasing concentration of NH4+, leading to the acceleration of electron transfer from C60•- to O2." @default.
• W2036865212 created "2016-06-24" @default.
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• W2036865212 date "2006-09-27" @default.
• W2036865212 modified "2023-09-24" @default.
• W2036865212 title "Activation of Electron-Transfer Reduction of Oxygen by Hydrogen Bond Formation of Superoxide Anion with Ammonium Ion" @default.
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• W2036865212 doi "https://doi.org/10.1021/jp064115m" @default.
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