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- W2036869099 abstract "A series of chromium(III) complexes of the type, [Cr(bpdo)n(en)3−n]3+ was obtained by preparing two new complexes, n=1 and 2, where bpdo denotes 2,2′-bipyridyl N,N′-dioxide. Each of the bpdo complexes gave only one pair of enantiomers, which were resolved by an SP-Sephadex column chromatographic or a chemical method. The circular dichroism spectra of the resolved complexes were compared with those of the related complexes of the known absolute configuration. The [Cr(bpdo)3]3+ complex in water racemizes spontaneously in dark. The rate is independent of the concentrations of the complex, acid, and the free ligand, and an intramolecular racemization mechanism is suggested." @default.
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- W2036869099 date "1979-03-01" @default.
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- W2036869099 title "Preparation and Resolution of a Series of Chromium(III) Complexes Containing 2,2′-BipyridylN,N′-Dioxide and Ethylenediamine" @default.
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- W2036869099 doi "https://doi.org/10.1246/bcsj.52.761" @default.
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