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• W2037011819 abstract "New complexes of Ph2P(CH2)nP(O)Ph2 (n = 1 (dppmO), n = 2 (dppeO)) and Ph2P(CH2P(S)Ph2 (dppmS) have been synthesized. These include mono- and di-nuclear metal carbonyl derivatives of chromium, molybdenum and manganese. The cationic complexes, [Rh(COD) L]X (L = dppmO, dppeO, X = PF6; L = dppmS; X = Cl, ClO4 PF6), the dimers [RhCl(CO)dppmS)] 2 and [PdCl2(dppmS)]2, and the mononuclear complexes [IrCl(COD)L] (L = dppmO, dppeO and dppmS; COD, cis-1,5-cyclooctadiene) and [PtCl2(dppmS)2] have also been prepared. The modes of coordination of the ligands have been established spectroscopically. All the dppmS complexes involve [P,S]-bidentate coordination of the ligand. The rhodium cations contain [PO]-chelated dppmO and dppeO. The complex [MO2(CO)2(dppeO)2] is believed to involve [P]- and [η6-C 6H5]-coordination. All other complexes contain unidentate [P]-bound ligands." @default.
• W2037011819 created "2016-06-24" @default.
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• W2037011819 date "1994-03-01" @default.
• W2037011819 modified "2023-09-26" @default.
• W2037011819 title "Some transition metal complexes of Ph2P(CH2)nP(O)Ph2 (n = 1, 2) and Ph2P(CH2) P(S)Ph2" @default.
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• W2037011819 doi "https://doi.org/10.1016/0022-328x(94)88012-3" @default.
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