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- W2037012007 abstract "Holeburning spectra from 1 ps to 1.2 ns have been measured for dimethyl-s-tetrazine dissolved in glycerol triacetate. Clean excitation of the well-separated 0–0 vibronic transition insures that only solvent dynamics contribute to the hole broadening. The majority of the interaction relaxes in less than a picosecond, with a second process relaxing in ≈ 2 ps. This solvation process is much faster than the 700 ps dielectric solvation of a highly polar solute in the same solvent, as measured by time-resolved Stokes shifts." @default.
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- W2037012007 title "Rapid solvation of a nonpolar solute measured by ultrafast transient holeburning" @default.
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- W2037012007 doi "https://doi.org/10.1016/s0009-2614(90)87182-q" @default.
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