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- W2037078891 abstract "α,β-Unsaturated ketones are no longer the missing dipolarophiles in catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides. In the presence of CuI−Fesulphos complexes as catalysts (5 mol %), these substrates combine high reactivity, wide substitution tolerance, moderate to good endo/exo selectivities, and high enantiocontrol. The endo/exo-diastereoselectivity of the reaction is strongly dependent on the cis or trans nature of the enone moiety." @default.
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- W2037078891 date "2008-12-18" @default.
- W2037078891 modified "2023-10-17" @default.
- W2037078891 title "Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Azomethine Ylides with α,β-Unsaturated Ketones" @default.
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- W2037078891 doi "https://doi.org/10.1021/ol802664m" @default.
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