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• W2037079102 abstract "The binding of gold nanoparticles capped with N-(2-mercaptopropionyl)glycine (Au@tiopronin) with double-stranded DNA has been investigated and quantified in terms of free energies by using two different approaches. The first approach follows the DNA conformational changes induced by gold nanoparticles using the CD technique. The second methodology consists in the use of pyrene-1-carboxaldehyde as a fluorescent probe. This second procedure implies the determination of the “true” free energy of binding of the probe with DNA, after corrections through solubility measurements. Working at different salt concentrations, the nonelectrostatic and electrostatic components of the binding free energy have been separated. The results obtained revealed that the binding is of nonelectrostatic character, fundamentally. The procedure used in this work could be extended to quantify the binding affinity of other AuNPs/DNA systems." @default.
• W2037079102 created "2016-06-24" @default.
• W2037079102 creator A5046645007 @default.
• W2037079102 creator A5080123802 @default.
• W2037079102 date "2014-01-01" @default.
• W2037079102 modified "2023-10-03" @default.
• W2037079102 title "Noncovalent Interactions of Tiopronin-Protected Gold Nanoparticles with DNA: Two Methods to Quantify Free Energy of Binding" @default.
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• W2037079102 doi "https://doi.org/10.1155/2014/143645" @default.
• W2037079102 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3920862" @default.
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