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• W2037084741 abstract "Mercaptoethanol (ME) and glutathione (GSH) react with 3-deoxyhexosulose (DH) with 2:1 stoichiometry, the initial reaction being first order with respect to DH but zero order with respect to H+ and thiol. The reaction is accelerated by glycine and two parallel rate-determining processes, one dependent on glycine concentration, are proposed. The rate constants are compared with those for the reaction of DH with sulphite species (S(IV)), which shows similar kinetic behaviour; however, the rate constant of the DH-thiol reaction is c. 2–3 times the value of that for the DH-S(IV) reaction but the effect of glycine is smaller by a factor of c. 3. Possible differences in mechanism are considered. The reaction of DH with cysteine shows complex behaviour. An initial rapid formation of a 1:1 adduct is followed by liberation of thiol. A mechanism involving the formation of a thiazolidine compound by addition of cysteine to a carbonyl group, followed by Strecker degradation, is suggested." @default.
• W2037084741 created "2016-06-24" @default.
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• W2037084741 creator A5073884326 @default.
• W2037084741 date "1991-01-01" @default.
• W2037084741 modified "2023-09-24" @default.
• W2037084741 title "Kinetics of the reaction of 3-deoxyhexosulose with thiols" @default.
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• W2037084741 doi "https://doi.org/10.1016/0308-8146(91)90020-o" @default.
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