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- W2037093593 abstract "Critical surface tension values γc were measured for poly(n-alkyl methacrylates) and copolymers of stearyl methacrylate with methacrylonitrile. Surface tension values γL of n-alkyl methacrylate increase with increasing side chain length: γL = 23.2 dynes/cm for methyl methacrylate to 33.2 dynes/cm for stearyl methacrylate, but γc values of poly(n-alkyl methacrylate) decrease with increasing side chain length: γc = 36.3 dynes/cm for poly(methyl methacrylate) to 20.8 dynes/cm for poly(stearyl methacrylate). The decrease in γc is attributed to a tighter packing of the alkyl chain with a greater concentration of the pendent CH3 group at the air/solid interface. Values of γc of copolymers hardly depended on the methacrylonitrile content in copolymers and did not satisfy the equation γc = N1γc1 + N2γc2 proposed by Lee. The difference in γc values for casting, annealing, and quenching films of poly(stearyl methacrylate) and the surface structure of copolymers were discussed using electron microscopy and measurement of melting point, heat of melting, and γc." @default.
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- W2037093593 date "1974-01-01" @default.
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- W2037093593 title "Effect of the length of branches on the critical surface tension of poly(n-alkyl methacrylates) and copolymers of stearyl methacrylate with methacrylonitrile" @default.
- W2037093593 doi "https://doi.org/10.1002/app.1974.070180115" @default.
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