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- W2037095917 abstract "We present results of a Monte Carlo simulation of dense melts of semi-flexible polymers using the bond-fluctuation model. The chosen Hamiltonian increases the chain stiffness upon cooling which in turn leads to glass-transition like freezing of the polymer mobility. Employing an efficient simulation algorithm, which is able to equilibrate the simulated systems to lower temperature than the Rouse-type algorithm showing the glassy freezing, we are able to observe an isotropic-nematic phase transition. This transition lies above the glass transition temperature one would extrapolate from the observed freezing behavior." @default.
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- W2037095917 date "1999-11-01" @default.
- W2037095917 modified "2023-10-02" @default.
- W2037095917 title "Competition between liquid-crystalline ordering and glassy freezing in melts of semiflexible polymers: A monte carlo simulation" @default.
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- W2037095917 doi "https://doi.org/10.1002/masy.19991460131" @default.
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