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- W2037103531 abstract "Homologous series of long-chain dialkylglycerylethers and the corresponding β-d-glucosides and β-d-cellobiosides were synthesized and studied with regard to their temperature-dependent monolayer properties. The main influence of carbohydrate moities was exerted on the surface pressure Fc at the collapse point and on the molecular area AL at the beginning of the expanded state as well as on the phase behavior. On introducing carbohydrate moities, AL and FC increased, attributable to increasing hydration and hydrogen bonding, respectively, whereas the monolayer became more expanded as a consequence of decreasing stabilization by alkyl-chain interactions. Enlargement of the hydrophilic headgroup by introducing carbohydrate moities therefore counteracts the effects of alkyl-chain lengthening on phase behavior." @default.
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- W2037103531 date "1983-05-01" @default.
- W2037103531 modified "2023-10-06" @default.
- W2037103531 title "Influence of carbohydrate moities on monolayer properties of dialkylglyceryletherglycosides, simple model compounds of the glycolipids of halophilic bacteria" @default.
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- W2037103531 doi "https://doi.org/10.1016/0021-9797(83)90390-9" @default.
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