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- W2037109712 abstract "We have discovered a novel compound Na0.12CrO2Ge0.18Ox•yH2O using a hydrothermal method. Its powder X-ray diffraction reveals a monoclinic unit cell with lattice parameters: a = 7.260 Å, b = 2.950 Å, c = 5.117 Å and β = 103.7°. A Rietveld analysis shows that this compound has a layered structure based on CrO2 sheets consisting of edge-shared CrO6 octahedra. Such a layered structure is commonly seen in many hexagonal Cr oxides such as NaCrO2. A heat treatment at 100 °C modifies the crystal structure without destruction of a layered structure based on Cr triangular-lattice, because H2O molecules among the CrO2 sheets are removed at high temperature. Magnetization measurements reveal a spin-glass behavior below Tg = 3 K." @default.
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- W2037109712 date "2011-04-01" @default.
- W2037109712 modified "2023-09-27" @default.
- W2037109712 title "Synthesis of Novel Chromium Oxide Using Hydrothermal Method and Analysis of its Magnetism and Structure" @default.
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- W2037109712 doi "https://doi.org/10.4028/www.scientific.net/ssp.170.29" @default.
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