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• W2037112676 abstract "Abstract In order to realize a molecular-based conductor exhibiting three-dimensional intermolecular interaction, twin donors (1 ∼ 4) have been designed. Electro-crystallization of the twin donor 1 gave three types of crystals (α-, β-, and β'-types). The crystal of α-type is composed of a pseudo cyclophane-shaped donor with 2:1 stoichiometry (I2, X, X = PF6, BF4, I3 − ClO4 −), exhibiting a semiconducting character (Ea = 5×10−2 eV). The crystal of β-type is obtained as another morphology of ClO4 salts. The structure of the donor is a cyclophane-shape with short intramolecular S…S distances. Insulating character of the salts can be rationalized mainly by the remote intermolecular S…S distances. On the other hand, 1°Cl·(H2O)x salts (β'-type) shows a metallic conductivity. The difference in crystal structures between β and β'-type salts may be explained by introduction of a polymeric hydrogenbonded counter ion system." @default.
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• W2037112676 date "1994-10-01" @default.
• W2037112676 modified "2023-10-01" @default.
• W2037112676 title "Characteristics of Molecular-Based Conductors Prepared by Twin Donors with a Hydrogen-Bonded Counter Ion System" @default.
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• W2037112676 doi "https://doi.org/10.1080/10587259408029772" @default.
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